Publications and Highlights

2024

Coskun, Oguz Kagan; Munoz, Miguel; Dongare, Saudagar; Dean, William; Gurkan, Burcu, "Understanding the electrode-electrolyte interfaces of ionic liquids and deep eutectic solvents" Langmuir, 2024

DOI: 10.1002/cphc.202300268


Dinis O. Abranches, Edward J. Maginn, Yamil J. Colón, "Boosting Graph Neural Networks with Molecular Mechanics: A Case Study of Sigma Profile Prediction" Journal of Chemical Theory and Computation, 2024

DOI: 10.1002/cphc.202300268


Drace Penley, Hazel Gerber, Mounesha Garaga, Nalinda Wickramasinghe, Steven Greenbaum, Edward Maginn, Yong Zhang, and Burcu Gurkan,"Impact of fluorination on Li+ solvation and dynamics in ionic liquid-hydrofluoroether locally concentrated electrolytes" Journal of Power Sources, 2024

DOI: 10.1002/cphc.202300268


William Dean, Miguel Muñoz, Juran Noh, Yangang Liang, Wei Wang, and Burcu Gurkan "Tuning and high throughput experimental screening of eutectic electrolytes with co-solvents for redox flow batteries" Electrochemica Acta, 2024

DOI: 10.1002/cphc.202300268


Giselle de Araujo Lima e Souza, Maria Enrica Di Pietro, Franca Castiglione, Patricia Fazzio Martins Martinez, Maleen Middendorf, Monika Schönhoff, Carla Cecilia Fraenza, Phillip Stallworth, Steven Greenbaum, Alessandro Triolo, Giovanni Battista Appetecchi, and Andrea Mele "Unveiling the transport properties of protic ionic liquids: Lithium ion dynamics modulated by the anion fluorine reservoir" Electrochemica Acta, 2024

DOI: 10.1002/cphc.202300268


Giselle de Araujo Lima e Souza, Maria Enrica di Pietro, Franca Castiglione, Patricia Fazzio Martins Martinez, Carla Cecilia Fraenza, Phillip Stallworth, Steven Greenbaum, Alessandro Triolo, Giovanni Battista Appetecchi, and Andrea Mele "Polymer electrolytes based on protic ionic liquids with perfluorinated anions for safe lithium-ion batteries" Electrochemica Acta, 2024

DOI: 10.1002/cphc.202300268


Rathiesh Pandian, Daniel Kim, Yong Zhang, Ibrahim Alfurayj, Desiree Mae Prado, Edward Maginn, and Clemens Burda, "Chain length and OH-spacing effects on diol-based deep eutectic solvents" J. Mol Liquids, 2024

DOI: 10.1002/cphc.202300268


William Parson and Clemens Burda, "Calculated solvent reorganization entropies, free energies, and fluctuations of the energy gaps for intramolecular electron transfer and excitation of the solvatochromic dye B30" The Journal of Chemical Physics, 2024

DOI: 10.1002/cphc.202300268


Vaishnavi Sree Jeganathan, Nicholas Sinclair, and Rohan Akolkar, "Methods—Meso-Scale Electrodes for Characterizing Diffusion-Reaction Properties of Redox-Active Organics in Viscous Electrolytes" Journal of the Electrochemistry Society, 2024

DOI: 10.1002/cphc.202300268


2023

Stephanie Spittle, Ibrahim Alfurayj, Benworth Bryce Hansen, Kaylie Glynn, William Brackett, Rathiesh Pandian, Clemens Burda, and Joshua Sangoro, "Enhanced Dynamics and Charge Transport at the Eutectic Point: A New Paradigm for the Use of Deep Eutectic Solvent Systems" JACS Au, 2023

DOI: 10.1002/cphc.202300268


Ibrahim Alfurayj, Carla Cecilia Fraenza, Rathiesh Pandian, Steve Greenbaum, Clemens Burda, "Nuclear Magnetic Resonance Relaxation Pathways in Electrolytes for Energy Storage" International Journal of Molecular Sciences, 2023

DOI: 10.1002/cphc.202300268


Ibrahim Alfurayj, Carla Cecilia Fraenza, Rathiesh Pandian, Steve Greenbaum, Clemens Burda, "Solvation dynamics of choline fluoride in ethylene glycol – Water mixtures" Journal of Molecular Liquids, 2023

DOI: 10.1002/cphc.202300268


Kevin Echelberry, Henrik Burda, Preston Willis, William Parson, Clemens Burda, "Temperature-Dependent Solvent Reorganization Entropies, Free Energies, and Transition Dipole Strengths for the Photoexcitation of Reichardt's Dye B30" The Journal of Chemical Physics, 2023

DOI: 10.1002/cphc.202300268


O. K. Coskun, S. Dongare, B. Doherty, A. Klemm, M. E.  Tuckerman, and B. Gurkan, "Tailoring Electrochemical CO2 Reduction on Copper by Reactive Ionic Liquid and Native Hydrogen Bond Donors" ACS Central Science, 2023

DOI: 10.1002/cphc.202300268


Nora Shaheen, Bethany Kersten, Rohan Akolkar, "Mathematical Framework Underlying the In Situ Electrochemical Diagnosis of Adsorbed Intermediates Formed during Redox Reactions at Electrode Surfaces," Journal of the Electrochemical Society, 2023

DOI: 10.1002/cphc.202300268


Desiree Prado, Xiaochen Shen, Robert Savinell, Clemens Burda, "Hydrodynamic Voltammetry of Fe2+/Fe3+ in Aqueous Deep Eutectic Sovents for Sustainable Redox Flow Batteries," Electrochemica Acta, 2023

DOI: 10.1002/cphc.202300268


Ibrahim Alfurayj, Rathiesh Pandian, Sarah Springer, Clemens Burda, "Choline Flouride-Ethlyne Glycol Deep Eutectic Solvent Mixture-Synthesis and Physiochemical Properties," J. Mol Liquids, 2023

DOI: 10.1002/cphc.202300268


Carla C. Fraenza and Steven G. Greenbaum, "Broadband NMR relaxometry as a powerful technique to study molecular dynamics of ionic liquids," ChemPhysChem, 2023

DOI: 10.1002/cphc.202300268


Dinis O. Abraches, Edward J. Maginn, Yamil J. Colón, "Activity Coefficient Acquisition with Thermodynamics-Informed Active Learning for Phase Diagram Construction," AIChE Journal, 2023

DOI: 10.1002/aic.18141


2022

Zhang, Yong; Klein, Jeffrey; Akolkar, Rohan; Gurkan, Burcu; Maginn, Edward, "Solvation Structure, Dynamics and Charge Transfer Kinetics of Cu2+ and Cu+ in Choline Chloride Ethylene Glycol Electrolytes,"  J. Phys. Chem. B, 2022 

DOI: 10.1021/acs.jpcb.2c04798


R. Ghahremani, W. Dean, N. Starvaggi, I. Alfurayi, C. Burda, E. Pentzer, J. Wainright, "Redox-Active Eutectic Electrolye with Viologen and Feffocene Derivatives for Flow Battery," ACS Applied Materials and Interfaces, 2022 

DOI: 10.1021/acsami.2c18546


R.Ghahremani, R. Savinell, B. Gurkan, "Perspective-Hydrogen bonded concentrated electrolytes for redox flow batteries: limitations and prospects," J. Electrochemical Society, 2022 

DOI: 10.1149/1945-7111/ac58c6


A.Imel, B. Barth, D. Hayes,M. Dadmun, T. Zawodzinski, "Microemulsions as Emerging Electrolytes: The Correlation of Structure to Electrochemical Response," ACS Applied Materials and Interfaces, 2022 

DOI: 10.1021/acsami.2c00181


Drace Penley, Xiaoyu Wang, Yun-Yang Lee, Mounesha N Garaga , Raziyeh Ghahremani, Steve Greenbaum, Edward J. Maginn, Burcu Gurkan,"Lithium Solvation and Mobility in Ionic Liquid Electrolytes with Asymmetric Sulfonyl-Cyano Anion," Journal of Chemical and Engineering Data, 2022

DOI: 10.1021/acs.jced.2c00294


Tony G Feric, Sara T Hamilton, Md Ashraful Haque, Javad Jeddi, Joshua Sangoro, Mark D Dadmun, Ah‐Hyung Alissa Park, "Impacts of Bond Type and Grafting Density on the Thermal, Structural, and Transport Behaviors of Nanoparticle Organic Hybrid Materials-Based Electrolytes," Advanced Functional Materials, 2022

DOI: 10.1002/adfm.202203947


N. Shaheen, W. Dean, D. Penley, B. Kersten, J. Rintamaki, M. Vukmirovic, B. Gurkan, R. Akolkar, "Electro–Oxidation of Nitroxide Radicals: Adsorption–Mediated Charge Transfer Probed Using SERS and Potentiometry," J. Electrochemical Society, 2022 

DOI: 10.1149/1945-7111/ac7082


X. Shen, N. Sinclair, C. Kellamis, B. Gurkan, J. Wainright, R. Savinell, "Effects of alkyl chain length and halide anion on hydrogen bonding in eutective solvents," Journal of Molecular Liquids, 2022

DOI: 10.1149/MA2022-02301102mtgabs


Tamar Zelovich, Thorsten Hansen, Mark E. Tuckerman, "A Green's Function Approach for determining Surface Induced Broadening and Shifting of Molecular Energy Levels," Nano Letters, 2022 

DOI: 10.1021/acs.nanolett.2c02910 


W. Dean, D. Penley, Y. Lee, R. Ghahremani, S. Dongare, B. E. Gurkan, "Anion Effects on the Interfacial Structure and Bulk Physical Properties in Choline-Based Hydrogen-Bonded Electrolytes," The Journal of Physical Chemistry C, 2022.
DOI: 10.1021/acs.jpcc.2c01901 


D. Penley, X. Wang, Y. Lee, M. N. Garaga, R. Ghahremani, S. Greenbaum, E. J. Maginn, B. E. Gurkan, "Lithium Solvation and Mobility in Ionic Liquid Electrolytes with Asymmetric Sulfonyl-Cyano Anion," Journal of Chemical & Engineering Data, 2022.
DOI: 10.1021/acs.jced.2c00294 


M. R. Hassan, B. A. Colon, J. Russell, T. R. Calhoun, "Small Molecule Sorting: A Fluorescence Study of Microemulsions," J. Phys. Chem. B, 2022.
DOI: 10.1021/acs.jpcb.2c02774


S. T. Hamilton, T. G. Feric, A. Gladysiak, N. M. Cantillo, T. A. Zawodzinski, A. A. Park, "Mechanistic Study of Controlled Zinc Electrodeposition Behaviors Facilitated by Nanoscale Electrolyte Additives at the Electrode Interface," ACS Applied Materials & Interfaces, 2022.
DOI: 10.1021/acsami.1c23781


A. E. Imel, B. Barth, D. G. Hayes, M. Dadmun, T. Zawodzinski, "Microemulsions as Emerging Electrolytes: The Correlation of Structure to Electrochemical Response," ACS Applied Materials & Interfaces, 2022.
DOI: 10.1149/1945-7111/ac7082


N. Shaheen, W. Dean, J. Rintamaki, M. B. Vukmirovic, B. E. Gurkan, R. Akolkar, "Electro-oxidation of nitroxide radicals: Adsorption-mediated charge transfer probed using SERS and potentiometry,"  Journal of the Electrochemical Society, 2022.
DOI: 10.1149/1945-7111/ac7082


J. M. Klein, H. W. Wang, R. L. Sacci, J. F. Browning, B. Gurkan, "Smooth Modified Surfaces of Silicon for the Study of Ionic Liquid Interfaces by Neutron Reflectometry", ACS Applied Electronic Materials, 2022.
DOI: 10.1021/acsaelm.1c01351


S. T. Hamilton, T. G. Feric, S. Bhattacharyya, N. M. Cantillo, S. G. Greenbaum, T. A. Zawodzinski, A. Park, "Nanoscale Hybrid Electrolytes with Viscosity Controlled Using Ionic Stimulus for Electrochemical Energy Conversion and Storage", JACS Au, 2022.
DOI: 10.1021/jacsau.1c00410


Raziyeh Ghahremani, Robert F. Savinell and Burcu Gurkan, "Hydrogen Bonded Concentrated Electrolytes for Redox Flow Batteries: Limitations and Prospects", Journal of The Electrochemical Society, 2022.
DOI: 10.1149/1945-7111/ac58c6


C. C. Fraenza and S. G. Greenbaum, "Broadband NMR relaxometry of electrolytes for energy storage", Chemical Physics Reviews, 2022.
DOI: 10.1063/5.0076580


Y. Zhang, H. Squire, B. Gurkan, and E. J. Maginn, "Refined Classical Force Field for Choline Chloride and Ethylene Glycol Mixtures over Wide Composition Range", Journal of Chemical & Engineering Data, 2022.
DOI: 10.1021/acs.jced.1c00841


S. Spittle, D. Poe, B. Doherty, C. Kolodziej, L. Heroux, M. A. Haque, H. Squire, T. Cosby, Y. Zhang, C. Fraenza, S. Bhattacharyya, M. Tyagi, J. Peng, R. A. Elgammal, T. Zawodzinski, M. Tuckerman, S. Greenbaum, B. Gurkan, M. Dadmun, E. J. Maginn, and J. Sangoro, "Evolution of Microscopic Heterogeneity and Dynamics in Choline Chloride-based Deep Eutectic Solvents", Nature Communications, 13, 219, 2022.
DOI: 10.1038/s41467-021-27842-z


C. C. Fraenza, R. A. Elgammal, M. N. Garaga, S. Bhattacharyya, T. A. Zawodzinski, and S. G. Greenbaum, "Dynamics of Glyceline and Interactions of Constituents: A Multi-technique NMR study", The Journal of Physical Chemistry B, 126, 4, 890-905, 2022.
DOI: 10.1021/acs.jpcb.1c09227


A. E. Imel, B. Barth, D. G. Hayes, M. Dadmun, T. Zawodzinski, "Microemulsions as Emerging Electrolytes: The Correlation of Structure to Electrochemical Response", ACS Applied Materials & Interfaces, 2022. 

DOI: 10.1021/acsami.2c00181


2021

B. Barth, A. Imel, K. M. Nelms, G. A. Goenaga, T. Zawodzinski, "Microemulsions: Breakthrough Electrolytes for Redox Flow Batteries", Frontiers in Chemistry, 2021.
DOI: 10.1016/j.joule.2020.12.004


Matthew A. Harris, Thomas Kinsey, Durgesh V. Wagle, Gary A. Baker and Joshua Sangoro, "Evidence of a liquid–liquid transition in a glass-forming ionic liquid", PNAS, 2021.
DOI: 10.1073/pnas.2020878118


J. Peng, Y. Xiao, A. Imel; B. Barth, N. Cantillo, K. M.Nelms, T. A. Zawodzinski, "Electrolyte effects on the electrochemical performance of microemulsions", Electrochimica Acta, 2021.
DOI: 10.1016/j.electacta.2021.139048


S. Overa, T. G. Feric, A. Park, F. Jiao, "Tandem and Hybrid Processes for Carbon Dioxide Utilization", Joule, 2021.
DOI: 10.1016/j.joule.2020.12.004


T. G. Feric, S. T. Hamilton, and A. Park, "Insights into the Enhanced Oxidative Thermal Stability of Nanoparticle Organic Hybrid Materials Developed for Carbon Capture and Energy Storage", Energy & Fuels, 2021.
DOI: 10.1021/acs.energyfuels.1c03243


Xiaochen Shen, Nicholas Sinclair, Jesse Wainright, Adam Imel, Brian Barth, Thomas Zawodzinski and Robert F. Savinell, "A Study of Ferrocene Diffusion in Toluene/Tween 20/1-Butanol/Water Microemulsions for Redox Flow Battery Applications", Journal of The Electrochemical Society, 2021.
DOI: 10.1149/1945-7111/ac0b26


X. Shen, N. Sinclair, J. Wainright and R. F. Savinell, "Methods? Analyzing Electrochemical Kinetic Parameters in Deep Eutectic Solvents Using an Extended Butler-Volmer Equation", Journal of The Electrochemical Society, 2021.
DOI: 10.1149/1945-7111/ac006a


Ibrahim Alfurayj, Carla Cecilia Fraenza, Yong Zhang, Rathiesh Pandian, Stephanie Spittle, Bryce Hansen, William Dean, Burcu Gurkan, Robert Savinell, Steve Greenbaum, Edward Maginn, Joshua Sangoro, and Clemens Burda, "Solvation Dynamics of Wet Ethaline: Water is the Magic Component", The Journal of Physical Chemistry B, 125, 31, 8888-8901, 2021.
DOI: 10.1021/acs.jpcb.1c04629


Jing Peng, Nelly M. Cantillo, Ye Xiao, K. McKensie Nelms, Lacey S. Roberts, Gabriel Goenaga, Adam Imel, Brian Andrew Barth, Mark Dadmun, Douglas G. Hayes and Thomas Zawodzinski, "Decoupling Conductivity and Solubility in Electrolytes Using Microemulsions", Journal of The Electrochemical Society, 2021.
DOI: 10.1149/1945-7111/ac180b


Nicholas S. Sinclair, Xiaochen Shen, Evan Guarr, Robert F. Savinell and Jesse S. Wainright, "Electrochemical Decomposition of Primary Alcohol Groups in Deep Eutectic Solvents", Journal of The Electrochemical Society, 2021.
DOI: 10.1149/1945-7111/ac2d14


Tony G. Feric, Sara T. Hamilton, Nelly M. Cantillo, Adam E. Imel, Thomas A. Zawodzinski, and Ah-Hyung Alissa Park, "Dynamic Mixing Behaviors of Ionically Tethered Polymer Canopy of Nanoscale Hybrid Materials in Fluids of Varying Physical and Chemical Properties", The Journal of Physical Chemistry B, 2021.
DOI: 10.1021/acs.jpcb.1c00935


Mounesha N. Garaga, Nishani Jayakody, Carla C. Fraenza, Boris Itin, Steven Greenbaum, "Molecular-level insights into structure and dynamics in ionic liquids and polymer gel electrolytes", Journal of Molecular Liquids, 2021.
DOI: 10.1016/j.molliq.2021.115454


Guanhe Rim,   Noyonika Roy,   Diandian Zhao,   Shiho Kawashima,   Phillip E. Stallworth,   Steve G. Greenbaum  and  Ah-Hyung Alissa Park   , "CO2 Utilization in Built Environment via the PCO2 Swing Carbonation of Alkaline Solid Wastes with Different Mineralogy", Faraday Discussions, 2021.
DOI: 10.1039/D1FD00022E


Md Ashraful Haque, Tony G. Feric, Sara T. Hamilton, Ah-Hyung Alissa Park, Mark D. Dadmun, "Structure and Dispersion of Free and Grafted Polymer in Nanoparticle Organic Hybrid Materials-based Solutions by Small Angle Neutron Scattering", The Journal of Physical Chemistry C, 2021.
DOI: 10.1021/acs.jpcc.0c10790


Emmanuel Urandu Mapesa, Nelly M. Cantillo, Sara Triana Hamilton, Matthew A. Harris, Thomas A. Zawodzinski Jr., Ah-Hyung Alissa Park, Joshua Sangoro, "Localized and Collective Dynamics in liquid-like Polyethylenimine-based Nanoparticle Organic-Inorganic Hybrid Materials", Macromolecules, 2021.
DOI: 10.1021/acs.macromol.0c02370


Nicholas S. Sinclair, Derrick Poe, Robert F. Savinell, Edward J. Maginn, Jesse S. Wainright, "A Nitroxide Containing Organic Molecule in a Deep Eutectic Solvent for Flow Battery Applications ", J. Electrochem. Soc., 168, 020527, 2021.
DOI: 10.1149/1945-7111/abe28a


William Dean, Jeffrey Klein and Burcu Gurkan, "Do Deep Eutectic Solvents Behave Like Ionic Liquid Electrolytes? A Perspective from the Electrode-Electrolyte Interface2" Journal of The Electrochemical Society, 168, 026503, 2021.
DOI: 10.1149/1945-7111/abde83


2020

B. E. Gurkan, E. J. Maginn, and E. B. Pentzer, "Deep Eutectic Solvents: A New Class of Versatile Liquids", The Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c10099


Yun-Yang Lee, Drace Penley, Aidan Klemm, William Dean, and Burcu Gurkan, "Deep Eutectic Solvent Formed by Imidazolium Cyanopyrrolide and Ethylene Glycol for Reactive CO 2 Separations" ACS Sustainable Chemistry Engineering, 2020.
DOI: 10.1021/acssuschemeng.0c07217

 


Hansen, B. B.; Spittle, S.; Chen, B.; Poe, D.; Zhang, Y.; Klein, J. M.; Horton, A.; Adhikari, L.; Zelovich, T.; Doherty, B. W.; Gurkan, B.; Maginn, E. J.; Ragauskas, A.; Dadmun, M.; Zawodzinski, T. A.; Baker, G. A.; Tuckerman, M. E.; Savinell, R. F.; Sangoro, J. R., "Deep Eutectic Solvents: A Review of Fundamentals and Applications", Chemical Review, 121, 3, 1232-1285, 2020.
DOI: 10.1021/acs.chemrev.0c00385


Nora A. Shaheen,Mahesh Ijjada, Miomir B. Vukmirovic, and Rohan Akolkar, "Mechanism of Electrochemical Oxidation of Nitroxide Radicals in Ethaline Deep Eutectic Solvent" J. Electrochem. Soc., 167, 143505, 2020.
DOI: 10.1149/1945-7111/abc439


Jing Peng, Nelly M. Cantillo, K. McKensie Nelms, Lacey S. Roberts, Gabriel Goenaga, Adam Imel, Brian Andrew Barth, Mark Dadmun, Luke Heroux, Douglas G. Hayes, and Thomas Zawodzinski, "Electron Transfer in Microemulsion-Based Electrolytes" ACS Applied Materials and Interfaces, 2020.
DOI: 10.1021/acsami.0c07028


Nelly M. Cantillo, Maria Bruce, Sara T. Hamilton, Tony G. Feric, Ah-Hyung Alissa Park and Thomas A. Zawodzinski Jr., "Electrochemical Behavior of Copper Ion Complexed with Nanoparticle Organic Hybrid Materials" IOP Science, 2020.
DOI: 10.1149/1945-7111/aba158


Nishani K Jayakody, Carla C. Fraenza, Steven G. Greenbaum, David S. Ashby, and Bruce S. Dunn, "NMR Relaxometry and Diffusometry Analysis of Dynamics in Ionic Liquids and Ionogels for Use in Lithium Ion Batteries" Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c02755


Brian Chen, Sarah Mitchell, Nicholas Sinclair, Jesse Wainright, Emily Pentzer and Burcu Gurkan, "Feasibility of TEMPO-functionalized imidazolium, ammonium and pyridinium salts as redox-active carriers in ethaline deep eutectic solvent for energy storage", Molecular Systems Design and Engineering, 2020.
DOI: 10.1039/D0ME00038H


Jeffrey M. Klein, Henry Squire, William Dean, and Burcu E. Gurkan, "From Salt in Solution to Solely Ions – Solvation of MethylViologen in Deep Eutectic Solvents and Ionic Liquids", Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c03296


Yong Zhang, Derrick Poe, Luke Heroux, Henry Squire, Brian W. Doherty, Zhuoran Long,Mark Dadmun, Burcu Gurkan, Mark E. Tuckerman, and Edward J. Maginn, "Liquid Structure and Transport Properties of the Deep EutecticSolvent Ethaline", Journal of Physical Chemistry B, 124, 5251-5264, 2020.
DOI: 10.1021/acs.jpcb.0c04058


Miomir B. Vukmirovic, Radoslav R. Adzic, and Rohan Akolkar, "Copper Electrodeposition from Deep Eutectic Solvents – Voltammetric Studies Providing Insights into the Role of Substrate: Platinum vs. Glassy Carbon", Journal of Physical Chemistry B, 2020.
DOI: 10.1021/acs.jpcb.0c02735


X. Shen, N. Sinclair, J. Wainright, R. Akolkar, and R.F. Savinell, "Evaluating and developing a reliable reference electrode for choline chloride based deep eutectic solvents", Journal of the Electrochemical Society, 2020 167 (8).
DOI: 10.1149/1945-7111/ab913c


Guanhe Rim, Ariane Katrina Marchese, Phillip Stallworth, Steven G. Greenbaum, Ah-Hyung Alissa Park, "29 Si Solid State MAS NMR Study on Leaching Behaviors and Chemical Stability of Different Mg-Silicate Structures CO2 Sequestration", Chemical Engineering Journal, 396 (c). 
DOI: 10.1016/j.cej.2020.125204


L. Chang and A. J. Bard, "Electrochemical Characterization of Bromine Reduction to Tribromide in Individual Nitrobenzene-in-Water Emulsion Droplets",  Journal of The Electrochemical Society, 2020 167 (6).
DOI: 10.1149/1945-7111/ab80ab


Nora A. Shaheen, Ijjada Mahesh, Miomir B. Vukmirovic, Rohan Akolkar, "Hysteresis effects and roughness suppression efficacy of polyethylenimine additive in Cu electrodeposition in ethaline",  Electrochemistry Communications 2020 115 106721
DOI: 10.1016/j.elecom.2020.106721


2019

J.M. Klein; H. Squire; B. Gurkan, "Electroanalytical Investigation of the Electrode–Electrolyte Interface of Quaternary Ammonium Ionic Liquids: Impact of Alkyl Chain Length and Ether Functionality, The Journal of Physical Chemistry C, 124, 10, 5613-5623,  (2019).
DOI: 10.1021/acs.jpcc.9b08016


Dai Shen, Miomir B Vukmirovic, Rohan Akolkar, "Understanding the Role of Complexation in the Charge-Transfer Kinetics of the Cu2+ + e ↔ Cu1+ Redox Reaction in Ethaline Deep Eutectic Solvent", Journal of The Electrochemical Society, 166 (15), E526-E532 (2019)
DOI: 10.1149/2.1211915jes


Burcu Gurkan, Henry Squire, and Emily Pentzer, "Metal-Free Deep Eutectic Solvents: Preparation, Physical Properties, and Significance", The Journal of Physical Chemistry Letters 2019 10 (24), 7956-7964 (2019)
DOI: 10.1021/acs.jpclett.9b01980


2018

Dai Shen, Katherine Steinberg, Rohan Akolkar, “Avoiding Pitfalls in the Determination of Reliable Electrochemical Kinetics Parameters for the Cu2+→Cu1+ Reduction Reaction in Deep Eutectic Solvents”, Journal of The Electrochemical Society , 165 (14), E808-E815, 2018,
DOI: 10.1149/2.1011814jes